Bilex Minerals EABilex

Laboratory Services

Precious-Metals Testing Methods

Compare the analytical and physical methods available for suitable bullion, doré, ore, concentrates and other precious-metal materials.

Start with the material and the information you need. Bilex will help define an appropriate testing scope.

Bilex Fire Assay furnace laboratory.

Overview

Gold testing starts with the material

There is no single testing method that answers every question about gold. An ore sample presents a different analytical problem from a doré bar. A finished bullion bar requires a different approach again. The condition of the material, the way it has been sampled, the information the client needs and whether the material can be altered all influence the method we use.

At Bilex Minerals EA, testing is carried out in house using analytical and physical verification methods selected for the material and the decision the result needs to support.

Fire Assay

Fire Assay is used when precious metal content needs to be determined from a representative prepared portion. For ores and concentrates, the work normally includes controlled preparation, fusion with flux and a collector, separation of the precious metal bearing button, cupellation and a suitable final determination. Doré and bullion follow a different metallic sampling and cupellation route because the material is already metal rather than geological matrix. Gold and silver can be determined where requested.

XRF Analysis

XRF provides rapid elemental information without consuming the item during measurement. Bilex uses both handheld and desktop XRF systems. Suitable metallic surfaces are cleaned and polished where required, and more than one area can be measured when the purpose is to compare composition across the item. XRF is a surface region technique, so the result is interpreted with the condition and preparation of the measured area in mind.

ICP OES, AAS and ICP MS

These instrumental methods normally work from an appropriately prepared analytical solution. ICP OES can measure several selected elements from the same solution. AAS is well suited to targeted determination of selected elements and can also be used as an instrumental finish after Fire Assay collection. ICP MS is used where very high sensitivity or trace level information is required. Each depends on suitable digestion or other preparation for the material being analysed.

PhotonAssay and Metallic Screen Fire Assay

Coarse gold distribution can make small analytical portions less representative. PhotonAssay measures a comparatively large prepared geological sample using high energy X rays and gamma detection while leaving the prepared sample intact. Metallic Screen Fire Assay uses a larger prepared mass, separates coarse and fine fractions, assays them separately and combines the results by their recorded weights. These methods answer different questions and are selected according to the sample.

Bullion integrity methods

Ultrasonic examination and density testing do not replace chemical or elemental analysis. Ultrasound sends high frequency sound through a suitable solid bar and examines returning echoes for internal boundaries, voids or inclusions. Hydrostatic density testing compares mass with displaced volume to determine whether the physical density is consistent with the expected material. Used alongside XRF or assay results, they can provide a broader picture of a bullion item.

Choosing the right method

Clients are not expected to select an analytical method in advance. The material form, approximate quantity, testing objective and whether destructive sampling is permitted are sufficient for our team to recommend an appropriate analytical scope.